• Damborg Swanson posted an update 6 months ago

    Ketamine and the traditional illicit drugs, such as amphetamine-type stimulants, cannabis and cocaine were most abundant and/or frequently detected in the samples collected, suggesting a higher use compared to NPS. The analyses of urine and wastewater is quick and a high number of attendees may be monitored anonymously by analysing only a few samples which allows identifying the local profiles of use of different drugs within a wide panel of psychoactive substances. This approach contributes to the development of an efficient surveillance system which can provide timely insight in the trends of NPS and illicit drugs use. Aquatic organisms such as bivalves are particularly sensitive to seasonal fluctuations associated with climate changes. Energy metabolism management is also closely related to environmental fluctuations. Changes in both biotic and abiotic conditions, such as the reproduction status and temperature respectively, may affect the organism energy status. A bivalve sentinel species, Dreissena polymorpha was sampled along its one-year reproduction cycle in situ (2018-2019) to study natural modulations on several markers of energy metabolism regarding seasonal variations in situ. A panel of different processes involved in energy metabolism was monitored through different functions such as energy balance regulation, mitochondrial density, and aerobic/anaerobic metabolism. The typical schema expected was observed in a major part of measured responses. However, the monitored population of D. polymorpha showed signs of metabolism disturbances caused by an external stressor from April 2019. Targeting a major part of energy metabolism functions, a global analysis of responses suggested a putative impact on the mitochondrial respiratory chain due to potential pollution. This study highlighted also the particular relevance of in situ monitoring to investigate the impacts of environmental change on sentinel species. High temporal-resolution VOC concentration data can provide detailed and important temporal variations of VOC species and emission sources, which is not possible when using coarse temporal-resolution data. In this study, we utilized the positive matrix factorization (PMF) model to conduct source apportionment of hourly concentrations of nineteen VOC species and CO measured at the Mong Kok air quality monitoring station, operated by the Hong Kong Environmental Protection Department, from January 2013 to December 2014. The PMF analysis of the hourly dataset (PMF_Hourly) identified five sources, including liquefied petroleum gas (LPG) (contribution of 45%), gasoline exhaust (21%), combustion (20%), biogenic emission (9%), and paint solvents (6%). The diurnal patterns of VOC emissions from identified sources are likely to be affected by the strength of emissions, variation of the planetary boundary layer height, and photochemical reactions. In addition, the PMF analyses of hourly and 24-hour averaged data of the hourly-resolved data (PMF_Hourly and PMF_Daily) were generally comparable, but the time series of VOC emissions from PMF_Hourly could not be well captured by PMF_Daily for two local VOC sources of gasoline exhaust and LPG. This study highlights the benefit of high temporal-resolution measurement data in apportioning VOC sources, hence providing critical information on VOC emission sources (e.g., diurnal variations) for controlling VOC emissions effectively. V.This work focuses on improving the biodegradability of hospital urines polluted with antibiotics by electrochemical advanced oxidation processes (EAOPs). To do this, chloramphenicol (CAP) has been used as a model compound and the influence of anodic material (Boron Doped Diamond (BDD) and Mixed Metal Oxide (MMO)) and current density (1.25-5 mA cm-2) on the toxicity and the biodegradability was evaluated. Results show that a complete CAP removal was attained using BDD anodes, being the process more efficient at the lowest current density tested (1.25 mA cm-2). Conversely, after passing 4 Ah dm-3, only 35% of CAP removal is reached using MMO anodes, regardless of the current density applied. Furthermore, a kinetic study demonstrated that there is a clear competitive oxidation between the target antibiotic and the organic compounds naturally contained in urine, regardless the current density and the anode material used. During the first stages of the electrolysis, acute toxicity is around 1% EC50 but it increases once CAP and its organic intermediates have been degraded. The formation and accumulation of inorganic oxidants may justify the remaining acute toxicity. This also helps to explain the trend observed in the rapid biodegradability assays. Finally, a 60% of standard biodegradability (Zahn-Wellens test) was achieved which suggests that electrochemical oxidation with BDD anodes could be the most appropriate technology to reduce the hazard of hospital urines at the operating conditions tested. The largest contributor to pollutant emissions is the sintering process in steel industry. BGJ398 chemical structure Ultra-low emission policy for the Chinese steel industry states that emission concentrations of particulate matter, SO2 and NOx should not exceed 10, 35 and 50 mg/m3 respectively. The emission concentrations of the steel industry are the same as the ultra-low emission policy for the coal-fired power industry, but the pollutant control technologies of the two industries are different. Life cycle assessment method is applied to analyze the latest ultra-low treatment process for sintering flue gas emissions which includes electrostatic precipitation, ozone oxidation, wet desulfurization, wet denitration, condensation dehumidification and wet electrostatic precipitation. Following this novel ultra-low emission treatment, the concentrations of particulate matter, SO2, NOx, and PCDDs in the sintering flue gas decreased very significantly, attaining the new emission standard. With 1 ton of sinter as the functional unit and “cradle to gate” as the system boundary, the environmental impact of the process is 0.1811 and the total economic cost is 172.79 RMB, of which internal cost is 34.64 RMB and external cost is 138.15 RMB. The main environmental impacts result from applying the wet denitration and ozone oxidation processes. Sodium sulfite in the wet denitration process, and electricity and liquid oxygen in the ozone oxidation process are the key inputs that cause environmental impact. These findings are useful for a further optimization of the ultra-low emissions process from both the environmental and economic perspective, which is applicable in other regions of the world.

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