-
Bradford Swanson posted an update 6 months ago
In this study, a photocatalytic reactor with a novel engineering design has been used for the extended degradation of sulfamethazine (SMZ). The reactor employed four consecutive stainless-steel plates immobilized by tungsten-dope TiO2 (W-TiO2) using polysiloxane. The characterization of W-TiO2 by X-ray diffraction (XRD), Raman spectroscopy, and energy-dispersive X-ray (EDX) denoted successful doping of tungsten in the lattice of anatase crystals of TiO2 suggesting a high photocatalytic activity under UV and visible light. A Box-Behnken experimental design was employed for the optimization of the operating parameters such as solution pH, flow rate, and the initial SMZ concentration. The residual SMZ concentration was below the detection limit after 30 min of the photocatalytic reaction under the optimum operating conditions. A highly remarkable degradation of SMZ was observed in five consecutive cycles, which reveals an extended stable photocatalytic activity offered by the reactor design. The transformation products were identified by tandem mass spectrometry, and they were employed to propose the degradation pathway. These results highlight the importance of using the photocatalysts in retained forms and open additional avenues for the practical application of photocatalysis in wastewater treatment.Sediments exposed to sunlight can serve as an important source of dissolved organic carbon (DOC) and nutrients to overlying waters. However, the photochemical release processes of dissolved organic matter (DOM) from resuspended sediments and the characteristics of photoreleased DOM are not fully understood. In this study, excitation-emission matrix fluorescence combined with parallel factor analysis (EEMs-PARAFAC) was used to study the photochemical release of DOM qualitatively and quantitatively. The EEMs-PARAFAC demonstrated that the photoreleased DOM is dominated by humic-like substances, and the photorelease process could be consist of the photoproduction and photodegradation of DOM. The concurrent photodegradation may result in the underestimation of photoreleased DOM. Moreover, the significant increases in DOC content and fluorescence intensity of humic-like components along with increasing nitrate and ferric ion indicated that nitrate and ferric ion could facilitate the photoproduction of DOM through the photochemical produced hydroxyl radical. However, the decreases in DOC and fluorescence intensity were also observed at high concentration of nitrate and ferric ion, owing to the photodegradation of DOM by redundant hydroxyl radical. All of these results suggest that EEMs-PARAFAC is an effective and sensitive analytical technique for evaluating DOM photoreleased from suspended lake sediments and previous studies may underestimate photochemical release of DOM from sediments due to the overlook of the subsequently photodegradation of these released DOM. Thus, the photochemical release of DOM and its associated pollutants from suspended particles in shallow and eutrophic lakes should be more significant then should be paid more attention.This work aims to characterize, in mineral and chemical terms, the ore tailings related to the Mariana disaster (MG, Brazil), occurred on 5 November 2015, and assess its correlation with sediments found in the continental shelf adjacent to the Doce River mouth (ES, Brazil). This study uses samples of tailings and seabed sediments collected at the mouth of the Doce River from 2012 to 2019. Elemental compositions of all samples were determined by X-ray fluorescence measurements; however, Synchrotron Resonant X-Ray Diffraction proved to be a remarkable technique to characterize the crystallographic phases of iron present in sediments. Studies and analyzes of the sediment samples showed that the tailings have a notable feature of the iron-crystallographic phases, mainly observed in the period after the Fundão dam failure, as compared with sediments collected in the period before. This set of iron-containing mineral phases, here called the Iron Mineralogical Set (IMS), consists of the main phases of hematite and magnetite and the minority phases of goethite and greenalite and it is used as a marker of tailings. Mass ac magnetic susceptibility measures supported the concept of the IMS as a marker. It is suggested a relationship between the content of the IMS in the sediment samples as a function of the measures of mass magnetic susceptibility. The IMS had shown the influence of tailings on the sea bed sediment indicating that there is no possibility, at the current stage, of predicting how many years this material will still be at the seabed.Background Women in Sub-Saharan African experience socioeconomic barriers in the use of reproductive health care services. This paper analyzes the evidence on socioeconomic inequalities in reproductive health care utilization in Sub-Saharan Africa and identifies the variance in the estimates of these inequalities. Methods We performed a systematic review and meta-analysis of studies on socioeconomic inequalities in the use of reproductive health care services published between January 2008 and June 2019. selleck kinase inhibitor We used meta-regression to identify heterogeneity sources in reproductive care services use. Results Twenty-two studies were included and they reported 305 estimates of the concentration index for different reproductive health care services. We grouped the services into ten categories of reproductive health care services. Socioeconomic status was associated with inequality in reproductive health care use and was on average high, with a pro-wealthy inequality magnitude of the concentration index of 0.202. The meta-analysis indicated that inequality was highest for skilled childbirth services with an average concentration index of 0.343. The average concentration index for family planning and components of antenatal care was 0.268 and 0.142 respectively. Random-effects meta-regression showed that the heterogeneity in reproductive health care use was explained by contextual differences between countries. Conclusion The magnitude of inequality in reproductive health care use varies with the type of service and the focus on skilled childbirth services through user fees removal appears to have fostered inequality. The one-size-fits-all approach to reproductive health care initiatives has ignored differences in reproductive health care needs and the ability to overcome use barriers.