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Balslev Cheng posted an update 6 months, 3 weeks ago
The thermal decomposition model of flame-retardant polyethylene terephthalate (FRPET) fiber is essential for predicting its fire behavior and do relevant fire simulation. In this work, the thermal decomposition character of FRPET is investigated via thermogravimetric analysis at four heating rates. Two kinetic schemes are proposed based on the analysis of experimental data and model-free methods. The model-free methods (Friedman and advanced Vyazovkin methods) are employed to determine possible search range for particle swarm optimization algorithm with constriction factor (CFPSO). Thus, this coupled method could evaluate the kinetic parameters for two proposed schemes without initial guess. Both models could reasonably predict the experimental data with obtained parameters, and the second two-step consecutive model shows better performance. The performance of CFPSO on the second model is further compared with improved generalized simulated annealing algorithm, and CFPSO was found to be more effective. Furthermore, global sensitivity analysis was conducted via the Sobol method to investigate the influence of kinetic parameters for the second model on predicted results. The most influential parameters are ln A and E α of the second reaction and reaction order n of the third reaction.The 1,3-diaryl-β-carboline derivatives, including 3,4-dihydro variants, were synthesized via a multiple-step approach. check details These compounds possess rigid and twisted configurations, which are expected to exhibit unique optical properties. The absorption and fluorescence properties of the newly synthesized compounds were investigated. These synthetic 1,3-diaryl-β-carbolines displayed strong emission in the range of 387-409 nm and exhibited absolute photoluminescence quantum yields of up to 74%. Density functional theory calculations were performed to better elucidate the geometric, electronic, and optical properties of these novel 1,3-diaryl-β-carbolines.Photon-counting CT detectors are the next step in advancing CT system development and will replace the current energy integrating detectors (EID) in CT systems in the near future. In this context, the performance of PCCT was compared to EID CT for three clinically relevant tasks abdominal soft tissue imaging, where differentiating low contrast features is important; vascular imaging, where iodine detectability is critical; and, high-resolution skeletal and lung imaging. A multi-tiered phantom was imaged on an investigational clinical PCCT system (Siemens Healthineers) across different doses using three imaging modes macro and ultra-high resolution (UHR) PCCT modes and EID CT. Images were reconstructed using filtered backprojection and soft tissue (B30f), vascular (B46f), or high-resolution (B70f; U70f for UHR) kernels. Noise power spectra, task transfer functions, and detectability index were evaluated. For a soft tissue task, PCCT modes showed comparable noise and resolution with improved contrast-to-noise ratio. For a vascular task, PCCT modes showed lower noise and improved iodine detectability. For a high resolution task, macro mode showed lower noise and comparable resolution while UHR mode showed higher noise but improved spatial resolution for both air and bone. PCCT offers competitive advantages to EID CT for clinical tasks.Recently, multi-energy inter-pixel coincidence counter (MEICC) has been proposed for charge sharing correction and compensation for photon counting detectors (PCDs), which uses energy-dependent coincidence counters to record coincident events between multiple energy windows of a pixel-of-interest and those of neighboring pixels. A Monte Carlo (MC) simulation study was performed to assess the performance of MEICC; however, the performance might have been overestimated in a previous study. The charge sharing increases the number of photons recorded at a PCD pixel at the expense of the spatial resolution, and therefore, when spatially uniform flat-field x-ray signals are used, it gives PCDs with charge sharing more signals than a PCD without charge sharing. In this paper, we propose to use spatially modulated boxcar signals for evaluating the performances for high spatial frequency tasks because they provide consistent signals regardless of the presence of absence of charge sharing. The flat-field signals must bquantum efficiency of PCD with charge sharing.Severe acute respiratory syndrome coronavirus-2 (SARS-CoV-2) infection has triggered the COVID-19 pandemic. Several factors induce hypoxia in COVID-19. Despite being hypoxic, some SARS-CoV-2-infected individuals do not experience any respiratory distress, a phenomenon termed ‘silent (or happy) hypoxia’. Prolonged undetected hypoxia could be dangerous, sometimes leading to death. A few studies attempted to unravel what causes silent hypoxia, however, the exact mechanisms are still elusive. Here, we aim to understand how SARS-CoV-2 causes silent hypoxia.The emergence of severe acute respiratory disease (SARS-CoV-2) variants that cause coronavirus disease is of global concern. Severe acute respiratory disease variants of concern (VOC) exhibiting greater transmissibility, and potentially increased risk of hospitalization, severity and mortality, are attributed to molecular mutations in outer viral surface spike proteins. Thus, there is a reliance on using appropriate counter-disease measures, including non-pharmaceutical interventions and vaccination. The best evidence suggests that the use of frontline biocides effectively inactivate coronavirus similarly, including VOC, such as 202012/01, 501Y.V2 and P.1 that have rapidly replaced the wild-type variant in the United Kingdom, South Africa and Brazil, respectively. However, this review highlights that efficacy of VOC-disinfection will depend on the type of biocide and the parameters governing the activity. VOC are likely to be similar in size to the wild-type strain, thus implying that existing guidelines for use and re-use of face masks post disinfection remain relevant. Monitoring to avoid injudicious use of biocides during the coronavirus disease era is required as prolonged and excessive biocide usage may negatively impact our receiving environments; thus, highlighting the potential for alternative more environmental-friendly sustainable biocide solutions. Traditional biocides may promote cross-antimicrobial resistance to antibiotics in problematical bacteria. The existing filtration efficacy of face masks is likely to perform similarly for VOC due to similar viral size; however, advances in face mask manufacturing by way incorporating new anti-viral materials will potentially enhance their design and functionality for existing and potential future pandemics.
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