• Mcdonald Calderon posted an update 6 months, 3 weeks ago

    Rutin is a polyphenol with excellent therapeutic potential and good safety profile, but the poor bioavailability restricts its application as a functional ingredient. However, this limitation may be mitigated by encapsulation. In this study, promising prospects of starch nanoparticles (SNPs) produced via ultra-sonication for rutin encapsulation was explored.The rutin encapsulated SNPs prepared from quinoa and maize starch (QR and MR) showed average particle sizes of 107 and 222 nm, encapsulation efficiency (EE) and loading efficiency (LE) values of 67.4 and 63.1%, 26.6 and 22.7%, zeta potential of – 18.0 and – 18.6 mv, respectively. Structural, physical and thermal properties were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), and differential scanning calorimetry (DSC). Simulated in vitro digestion showed increased rutin bioavailability with significantly higher (p less then 0.05) in vitro antioxidant activities in QR than MR. Overall, SNPs prepared using ultrasound have potential to encapsulate polyphenols for improved bioavailability.A surface defect sandwich-structural TiO2-x/ultrathin g-C3N4/TiO2-x direct Z-scheme heterojunction photocatalyst is successfully constructed. The results manifest the existence of oxygen vacancies, sandwich structure and direct Z-scheme heterojunction. Noticeably, TiO2-x/ultrathin g-C3N4/TiO2-x efficiently eliminates high toxic tetracycline hydrochloride by means of·O2-, h+ and·OH, whose removal rate is 87.7% during 90 min and the pseudo-first-order rate constant reaches up to 31.7 min-1 × 10-3. The extraordinary performance can be attributed to the special 3D structure, Z-scheme heterojunction expediting charge transfer and promoting the generation of active species, meanwhile the oxygen vacancies enhancing the spatial separation of photo-induced carriers. Moreover, various environmental factors are systematically explored by statistics. SO42-, NH3-N and pH exhibit an obvious impact on removal rate. Sunvozertinib supplier Meanwhile, TiO2-x/ultrathin g-C3N4/TiO2-x could also effectually remove tetracycline hydrochloride from complex actual-wastewater and exhibit high stability. Besides, the photocatalytic mechanism and degradation path of tetracycline hydrochloride are also elucidated.This study investigates the mineralogy, micro-morphology, chemical characteristics and oxidation toxicity of respirable dusts generated in underground coal mines. The active sampling was applied to collect airborne particulates with aerodynamic diameter urate, implying low- to medium level of oxidative stress. The result of this study can be applied globally by decision-makers to decrease hazardous exposure of mine workers to respirable dust.Microbial community compositions and functional profiles were analyzed in microcosms established using aquifer materials from a former automobile factory site, where 1,4-dioxane was identified as the primary contaminant of concern. Propane or oxygen biostimulation resulted in limited 1,4-dioxane degradation, which was markedly enhanced with the addition of nutrients, resulting in abundant Mycobacterium and Methyloversatilis taxa and high expressions of propane monooxygenase gene, prmA. In bioaugmented treatments, Pseudonocardia dioxanivorans CB1190 or Rhodococcus ruber ENV425 strains dominated immediately after augmentation and degraded 1,4-dioxane rapidly which was consistent with increased representation of xenobiotic and lipid metabolism-related functions. Although the bioaugmented microbes decreased due to insufficient growth substrates and microbial competition, they did continue to degrade 1,4-dioxane, presumably by indigenous propanotrophic and heterotrophic bacteria, inducing similar community structures across bioaugmentation conditions. In various treatments, functional redundancy acted as buffer capacity to ensure a stable microbiome, drove the restoration of the structure and microbial functions to original levels, and induced the decoupling between basic metabolic functions and taxonomy. The results of this study provided valuable information for design and decision-making for ex-situ bioreactors and in-situ bioremediation applications. A metagenomics-based understanding of the treatment process will enable efficient and accurate adjustments when encountering unexpected issues in bioremediation.This review focuses on the degradation kinetics and mechanisms of disinfection byproducts (DBPs) under UV and solar irradiation and in UV-based advanced oxidation processes (AOPs). A total of 59 such compounds are discussed. The processes evaluated are low pressure, medium pressure and vacuum UV irradiation, solar irradiation together with UV/hydrogen peroxide, UV/persulfate and UV/chlorine AOPs. Under UV and solar irradiation, the photodegradation rates of N-nitrosamines are much higher than those of halogenated DBPs. Among halogenated DBPs, those containing iodine are photodegraded more rapidly than those containing bromine or chlorine. This is due to differences in their bond energies (EN-N less then EC-I less then EC-Br less then EC-Cl). Molar absorption coefficients at 254 nm and energy gaps can be used to predict the photodegradation rates of DBPs under low pressure UV irradiation. But many DBPs of interest cannot be degraded to half their original concentration with less than a 500 mJ cm-2 dose of low pressure UV light. HO• generally contributes to less than 30% of the degradation of DBPs except iodo-DBPs in UV/H2O2 AOPs. Reaction mechanisms under UV irradiation and in HO•-mediated oxidation are also summarized. N-N bond cleavage initiates their direct UV photolysis of N-nitrosamines as C-X cleavage does among halogenated compounds. HO• generally initiates degradation via single electron transfer, addition and hydrogen abstraction pathways. Information on the reaction rate constants of SO4•- and halogen radicals with DBPs is rather limited, and little information is available about their reaction pathways. Overall, this review provides improved understanding of UV, solar and AOPs.In view of poor hydrothermal resistance of impregnation prepared catalysts (Cu5Ce5W9Ti-I), this paper aims to enhance thermal and hydrothermal resistance of Cu/Ce based catalysts for Hg0 oxidation via flame synthesis technology. The result found that the flame synthesis method could form nanoscale Cu10Ce10W9Ti-F particles with smaller lattice size (8-25 nm), more stable carrier structure and more oxygen vacancies. The inter-doping and inter-substitution of Ce, Cu and Ti oxides created more oxygen vacancies (Ce3+) and L-sites (O2-). Furthermore, the carrier TiO2 of Cu10Ce10W9Ti-F existed in form of highly thermostable rutile rather than anatase. High Hg0 oxidation efficiency (MOE) of 83.9-99.7% at 100-450 °C proved excellent oxidation activity of Cu10Ce10W9Ti-F catalyst. Moreover, the thermal and hydrothermal treatment (700 °C) only decreased MOE by less than 5% since L-sites kept fine thermostability of Cu10Ce10W9Ti-F. The flame synthesis was proven to be a promising catalyst preparation method to enhance thermal and hydrothermal resistance.

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